where k (M− 2 s− 1) can be determined from the
in the pH range 2 to 5, from 5 to 40 °C and 0.01 to 1 M.The effect of pH and ionic strength on the reaction suggest that the rates are due to
where H2A = H2CrO4, HA = HCrO4, H2B = H2SO3 and HB = HSO3. The overall rate expression over the investigated pH range can be determined from
k=kH2A–H2B(αH2A)(αH2B)2+kHA–H2B(αHA)(αH2B)2+kH2A–HB(αH2A)(αHB)2
with kH2A−H2B = 5.0 × 107, kHA–H2B = 1.5 × 106 and kH2A–HB = 6.7 × 107.Fe(III) in the range 1.5 to 20 μM exerts a small catalytic effect on the reaction and significantly lowers the initial concentration of Cr(VI) compared to the nominal value. Contrary to Fe(III), formaldehyde (20 to 200 μM) reacts with S(IV) to form the hydroxymethanesulfonate adduct (CH2OHSO3), which does not react with Cr(VI). Major cations Mg2+ and some minor elements such as Ba2+ and Cu2+ did not affect the rates. The application of this rate law to environmental conditions suggest that this reaction may have a role in acidic solutions (aerosols and fog droplets). This reaction becomes more important in the presence of high Fe(III) and low HMS concentrations, contributing to affect the atmospheric transport of chromium species and the distribution of redox species of chromium, which reach surface water from atmospheric depositions.  相似文献   
112.
大历十才子与方外隐逸诗人之隐逸诗比较     
张声怡 《广东海洋大学学报》2005,25(5):82-88
“吏隐”作为大历十才子的生活特征之一,也成为他们创作的题材,这与当时方外隐逸诗人因其不同的人生观照所创作的诗作相映成趣。方外隐逸诗人又可分为隐士诗人和诗僧两个群体,大历十才子和方外隐逸诗人之间体现出了完全不同的生命体验,方外隐逸诗人对真隐精神的写作与十才子的“伪隐”形成了鲜明的对比,就后者来说,现实的功利主义态度和价值上的物质取向使其隐逸诗作之精神内涵大打折扣。  相似文献   
113.
REVIEWS OF GEOGRAPHIC SOFTWARE     
《The Professional geographer》1986,38(4):425-430
Geographic Software Reviewed in this article: LIFE TABLES and the LESLIE MATRIX. CONDUIT MENTMAP2 . Lawrence W. Carstensen Jr . PC-MATLAB , Version 1.0. The Math Works, Inc. QUICKMAP , version 1.0. Sammamish Data Systems, Inc. SYSTAT: THE SYSTEM FOR STATISTICS , Version 2.1, Systat Inc. USA DISPLAY . Instant Tecall  相似文献   
114.
BOOK REVIEWS     
《The Professional geographer》1982,34(4):458-490
Books reviewed in this article: Aerial Photography and Remote Sensing. Terrain Analysis and Remote Sensing . JOHN R. G. TOWNSHEND , ed. Environmental Data Use in Computer-assisted Data Handling Systems: The Results of a Survey of Applications in the Pacific Northwest States . KENNETH E. GORDON . Applied Land Use: A Spatial Approach . JOHN F. LOUNSBURY , LAWRENCE M. SOMMERS , AND EDWARD A. FERNALD , eds. The Second Battle of New Orleans: A History of the Vieux Carre Riverfront-Expressway Controversy . RICHARD O. BAUMBACH , JR. AND WILLIAM E. BORAH . Cultural Environmental Archaeology . MYRA SHACKLEY . The Immoral landscape: Female Prostitution in Western Societies . RICHARD SYMANSKI . life Among the Poor in Cairo . UNNI WIKAN , translated by Ann Henning. Women, Work and Property in Northwest India . URSULA SHARMA . The Domestication of Women: Discrimination in Developing Societies . BARBARA ROGERS Economic Optimization in Locational and Transport Analysis . A. G. WILSON , J. D. COELHO , S. M. MACGILL , H. C. W. L. WILLIAMS . New Tools for Economic Development: The Enterprise Zone, Development Bank, and RFC . GEORGE STERNLIEB AND DAVID LISTOKIN , eds. Regional Wage Inflation . R. L. MARTIN , ed. Finding A Place For Energy-Siting Coal Conversion Facilities . FRANK J. CALZONETTI WITH MARK S. ECKERT . Environmental Management, Resources, and Systems Environmentalism. Second Edition . T. O'RIORDAN . Countryside Conservation . BRYN GREEN . Medical Spatial Diffusion: An Historical Geography of Epidemics in an Island Community . A. D. CLIFF , P. HAGGETT , J. K. ORD , AND G. R. VERSEY . Philosophy and Geographic Thought Order and Skepticism: Human Geography and the Dialectic of Science . RICHARD SZYMANSKI AND JOHN A. AGNEW . Measurement of Subjective Phenomena . D. F. JOHNSTON , ed. Conceptions of Space in Social Thought: A Geographic Perspective . ROBERT DAVID SACK . The Association of American Geographers: The First Seventy-five Years: 1904-1979 . PRESTON E. JAMES AND GEOFFREY J. MARTIN . The Life and Thought of Isaiah Bowman . GEOFFREY J. MARTIN . Physical River Basin Planning: Theory and Practice . SURANJIT K. SAHA AND CHRISTOPHER J. BARROW , eds. Soils and landforms: An Integration of Ceomorphology and Pedology . A. I. GERRARD Climatic Change and Society. Consequences of Increasing Atmospheric Carbon Dioxide . WILLIAM W. KELLOGG AND ROBERT SCHWARE . Political Political Redistrictings and Geographic Theory . RICHARD L. MORRILL . Population Studies in Spanish American Population History: Dell Plain Latin American Studies NO. 8 . DAVID J. ROBINSON , ed. Population Redistribution in the Midwest . CURTIS C. ROSEMAN , ANDREW J. SOFRANKO , AND JAMES D. WILLIAMS , eds. Geographical Perspectives on the Elderly . A. M. WARNES , ed. Regional Perspective On the American South . MERLE BLACK AND JOHN SHELTON REED , eds. The Prairies and Plains: Prospects for the 80s . JOHN R. ROGGE , ed. Rural Rural Settlement in an Urban World . MICHAEL BUNCE . Social Accident at Three Mile Island: The Human Dimensions . DAVID L. SILLS , C. P. WOLF , AND VIVIEN B. SHELANSKI , eds. The American Small Town: Twentieth-Century Place Images . JOHN JAKLE . Urban A House of My Own . SUSAN LOBO . The City: Patterns and Processes in the Urban Ecosystem . CHRISTOPHER H. EXLINE , GARY L. PETERS , AND ROBERT P. LARKIN . Movement in Cities . P. W. DANIELS AND A. M. WARNES . Urbanization and Urban Planning in Capitalist Society . MICHAEL DEAR AND ALLEN J. SCOT , eds.  相似文献   
115.
Unstable kinetic Alfvén wave in partially ionized plasma     
J. Vranjes  D. Petrovic  M. Kono 《Planetary and Space Science》2006,54(6):641-644
The stability of kinetic Alfven waves is discussed for a partially ionized plasma with a flux of ionizing electrons which balance the plasma particle losses. Accidental electromagnetic perturbations are shown to be unstable due to the energy change of ionizing electrons.  相似文献   
116.
近40年甘南草原生命地带偏移趋势及干湿变化   总被引:1,自引:0,他引:1       下载免费PDF全文
王建兵 《应用气象学报》2012,23(5):604-608
利用Holdridge生命地带系统对1971—2010年甘南草原的Holdridge生命地带偏移趋势及干湿变化进行分析,发现甘南草原目前仍属于青藏高原高寒植被地区的亚高山高寒草甸生命地带,但由于甘南草原生物温度明显升高,甘南草原南部和北部降水量呈现不同的变化趋势,位于青藏高原边坡地带的甘南草原的Holdridge生命地带距平均中心的偏移趋势逐年增大,甘南草原生态系统的稳定性在减弱;甘南草原潜在蒸散率以0.02/10 a~0.03/10 a趋势上升,其中以玛曲上升最明显,达0.03/10 a;20世纪90年代后,甘南草原呈明显的暖干化趋势,其中以位于南部的碌曲、玛曲变化最为明显,碌曲已由极湿润区转变为湿润区;玛曲有从极湿润区向湿润区过渡的趋势。影响甘南草原潜在蒸散率上升的主要气候因子是温度,其次为降水和空气湿度,温度上升是甘南草原暖干化的主要原因。  相似文献   
117.
网格地理信息服务生命周期管理研究     
葛文  成毅  孙亚飞  刘嵘 《测绘工程》2012,21(5):17-21
为了实现网格地理信息服务系统中服务资源的高效享用和可控管理,研究网格地理信息服务生命周期管理问题。从服务资源自身的生命周期、服务资源在注册中心中的生命周期和服务资源在虚拟组织中的生命周期三方面出发研究服务资源的生命周期管理问题。最后研究基于盟主的虚拟组织生命周期管理问题。  相似文献   
118.
风暴生命史雷达特征量反演   总被引:1,自引:0,他引:1       下载免费PDF全文
张家国  万玉发  王珏 《应用气象学报》2008,19(1):101-105
从风暴演变各阶段物理特征出发, 基于多普勒雷达观测的三维反射率因子, 定义物理量———单体重力势能。结果表明:单体重力势能是一个能够简洁、客观描述风暴单体整体强度的物理量; 利用该物理量可描述单体生命史为发展和减弱两个基本过程; 单体重力势能大小有助于辨别风暴类型和强度。同时, 生成和分析了风暴单体演变各阶段的反射率因子垂直廓线, 分析表明:在30~150 km的雷达观测范围内, 风暴单体的反射率因子垂直廓线 (降水廓线) 及其随时间的变化能较好地揭示风暴的垂直结构和生命史演变特征, 但没有用重力势能那样简洁。  相似文献   
119.
Life and habitable zones in the Universe     
Rami T.F. Rekola 《Planetary and Space Science》2009,57(4):430-433
Currently we are aware of only one biosphere in the entire Universe, our own. Various ongoing observational programmes are, however, attempting to locate more. These searches for extraterrestrial life are among the most challenging and interesting tasks of modern science. The Universe is immense, and even the distances to the nearest stars are beyond our present capabilities to traverse, so that search strategies must be thought through carefully in terms of how, where and what to search for. Life is undoubtedly more likely in some environments than others, and environmental criteria must be fulfilled for life to arise, survive, evolve and thrive. As search resources are limited we should concentrate our search on habitable zones that are suitable for the kind of life we can most easily recognise, in other words, searches should be guided by our own biosphere.  相似文献   
120.
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111.
The rates of the reduction of Cr(VI) with S(IV) were measured in deaerated NaCl solution as a function of pH, temperature and ionic strength. The rates of the reaction were found to be first order with respect to Cr(VI) and second order with respect to S(IV), in agreement with previous results obtained at concentrations two order higher than the present study. The reaction also showed a first-order dependence of the rates on the concentration of the proton and a small influence of temperature with an apparent energy of activation ΔHapp of 22.8 ± 3.4 kJ/mol. The rates were independent of ionic strength from 0.01 to 1 M. The rate of Cr(VI) reduction is described by the general expression
−d[Cr(VI)]/dt=k[Cr(VI)][S(IV)]2
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